Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
نویسندگان
چکیده
New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities.
منابع مشابه
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عنوان ژورنال:
دوره 10 شماره
صفحات -
تاریخ انتشار 2014